Saturday 30 April 2022

POLYATOMIC IONS

POLY-ATOMIC IONS
Ions that contained atoms of more than one element is known as poly-atomic ions.

Polyatomic ions are ions that are composed of two or more atoms that are covalently bonded together, and they carry an overall electric charge. These ions can be either positively or negatively charged, and they play an important role in chemistry and biochemistry.

Some examples of commonly encountered polyatomic ions include sulfate (SO4-2), nitrate (NO3-), carbonate (CO3-2), ammonium (NH4+), and phosphate (PO4-3).

Polyatomic ions are often involved in chemical reactions, where they act as reactants, products, or catalysts. For example, sulfate is often used as a reactant in the production of fertilizers, while phosphate is a key component of DNA and ATP (adenosine triphosphate), which is the primary energy source for most biological processes.

Polyatomic ions are also important in the context of acid-base chemistry, as they can act as either acids or bases depending on the situation. For example, nitrate can act as a base in the presence of a strong acid, while ammonium can act as an acid in the presence of a strong base.

Overall, polyatomic ions play an important role in many areas of chemistry and biology, and a good understanding of their properties and behaviors is essential for anyone studying these subjects.


NAME

SYMBOLS

VALENCY

HYDROXIDE

OH

-1

ACETATE

CH₃COO

-1

CYANIDE

CN

-1

CHLORATE

ClO3

-1

CHLORITE

ClO2

-1

NITRATE

NO3

-1

NITRITE

NO2

-1

SULPHATE

SO4

-2

SULPHITE

SO3

-2

PHOSPHATE

PO4

-3

PHOSPHITE

PO3

-3

PERMANGANATE

MnO4

-1

HYDROGEN CARBONATE

HCO3

-1

CARBONATE

CO3

-2

SILICATE

SiO3

-2

CHROMATE

CrO4

-2

DICHROMATE

Cr2O7

-2

AMMONIUM

NH4

+1



Examples of Compounds having hydroxide (OH) ions

 

Compound Name

Formula

Uses

Sodium Hydroxide

NaOH

It is also called Caustic Soda. Used in manufacturing of paper, textiles, soaps etc.

Potassium Hydroxide

KOH

Used in the manufacturing of soaps and detergents.

Calcium Hydroxide

Ca(OH)2

It is also called Slaked Lime. Used as a construction materials.

Aluminium Hydroxide

Al(OH)3

Used in Antacid to neutralize acidity in stomach and treat ulcers.

Magnesium Hydroxide

Mg(OH)2

Used in Antacid to neutralize acidity and indigestion, heartburn.

Ammonium Hydroxide

NH4OH

Used in as Cleaning agent.

Barium Hydroxide

Ba(OH)2

Used in the production of Lubricants.

 

Examples of Compounds having Acetate (CH3COO) ions

 

Compound Name

Formula

 Uses

Sodium Acetate

CH3COONa

 

Acetic Acid

CH3COOH

 

 

Examples of Compounds having Cyanide (CN) ions

 

Compound Name

Formula

 Uses

Potassium Cyanide

KCN

 

Hydrogen Cyanide

HCN

 

 

Examples of Compounds having Chlorate (ClO3) ions

 

Compound Name

Formula

 Uses

Potassium Chlorate

KClO3

 

Barium  Chlorate

Ba(ClO3)2

 

Calcium Chlorate

Ca(ClO3)2

 

Iron(III) Chlorate

Fe(ClO3)3

 

Zinc Chlorate

Zn(ClO3)

 





EXAMPLE: SOME COMMON COMPOUNDS CONTAINING HYDROXIDE IONS

Sodium Hydroxide NaOH
Potassium Hydroxide KOH
Calcium Hydroxide Ca(OH)₂
Aluminium Hydroxide Al(OH)₃

Acetate      (CH₃COO) (-1)
Sodium Acetate CH₃COONa

Cyanide.  (CN) (-1)
Potassium Cyanide KCN
Hydrogen Cyanide HCN

Chlorate (ClO₃) (-1)
Potassium Chlorate KClO₃

Chlorite (ClO₂) (-1)

Nitrate.    (NO₃) (-1)
Nitric Acid HNO₃
Potassium Nitrate KNO₃
Sodium Nitrate NaNO₃

Nitrite.     (NO₂) (-1)
Nitrous Acid HNO₂

Sulphate (SO₄) (-2)
Sodium Sulphate Na₂SO₄
Barium Sulphate BaSO₄
Zinc Sulphate ZnSO₄
Copper Sulphate CuSO₄



Sulphite.  (SO₃) (-2)
Phosphate (PO₄) (-3)
Phosphite. (PO₃) (-3)
Permanganate (MnO₄) (-1)
Hydrogen Carbonate (HCO₃) (-1)
Carbonate (CO₃) (-2)
Silicate (SiO₃) (-2)
Chromate (CrO₄) (-2)
Dichromate (Cr₂O₇) (-2)
Aluminate (AlO₃) (-3)
Ammonium (NH₄) (+1)

Thursday 28 April 2022

LECTURE 2: CHEMICAL EQUATIONS (CLASS X)

CHEMICAL EQUATIONS
The method of representing a chemical reaction with the help of symbols and formula of the substances involved in it, is known as a chemical equation. 

REACTANTS
The substances which take part in a chemical reaction are called reactants. 
The reactants are always written on the left hand side in an equation with a plus sign (+) between them. 
PRODUCTS
The new substances produced as a result of chemical reaction are called products. 
The products are always written on the right hand side in an equation with a plus sign (+) between them.

The arrow sign (→) is put in between the reactants and the products and always directed from left to right. 

A chemical equation is a short-hand method to represent a chemical reaction. 

TWO WAYS TO WRITE A CHEMICAL EQUATION

1. UNBALANCED CHEMICAL EQUATIONS. 
2. BALANCED CHEMICAL EQUATIONS. 

UNBALANCED CHEMICAL EQUATIONS
An unbalanced chemical equation has an unequal number of atoms of one or more elements in the reactants and products. 
Example:  H₂ + O₂ → H₂O
H atoms in Reactants = 2, in Products = 2
O atoms in Reactants = 2, in Products = 1

BALANCED CHEMICAL EQUATIONS
A balanced chemical equation has an equal number of atoms of different elements in the reactants and products. 
Example: Zn + H₂SO₄ → ZnSO₄ + H₂
Zn atoms in Reactants = 1, in Products = 1
H atoms in Reactants = 2, in Products = 2
S atoms in Reactants = 1, in Products = 1
O atoms in Reactants = 4, in Products = 4

BALANCING OF CHEMICAL EQUATIONS
The process of making the number of different types of atoms equal on both the sides of an equation is called balancing of chemical equation. 
(Steps are to be discussed in the class)

How to make a chemical equation more informative?
The chemical equation can be made more informative in three ways.
1. By indicating the physical states of the reactants and products.
2. By indicating the heat changes taking place in the reaction.
3. By indicating the conditions under which the reaction takes place. 

1. To indicate the Physical States of the Reactants and Products in an Equation.
We write 
For solids (s) , 
for liquids (l), 
for gas (g), 
for water solution or dilute (aq), 
for evolving gas ↑, 
for precipitates (insoluble solid product) ↓, 
Like 
Zn (s) + H₂SO₄(aq) → ZnSO₄ (aq) + H₂ (g) ↑

2. To indicate the heat changes in an equation

EXOTHERMIC REACTION
Those reactions in which heat is evolved are known as Exothermic Reactions.

Q. When calcium hydroxide reacts with carbon dioxide, white calcium carbonate precipitates and hydrogen gas evolved. Write the chemical reaction.
Ans. Ca(OH)₂ (aq) + CO₂ (g) → CaCO₃ (s)↓ + H₂O (l)
Q. What happens when we burn Methane ? Write its chemical reaction. 
Ans. When Methane (natural gas) burns in the presence of Oxygen from air, Carbon Dioxide and Water is formed along with a large quantity of heat. 
CH₄ (g) + 2O₂ (g) → CO₂ (g) + 2H₂O (l) + Heat energy
Burning of natural gas is an exothermic reaction. Infact, all combustion (burning) is exothermic reaction. 
Q. What happens when respiration takes place?
Ans. When glucose undergoes a slow combustion by combining with oxygen in our cells to produce energy in a process called respiration, carbon dioxide along with water and Energy is produced. 
C₆H₁₂O₆ (aq) + 6O₂ (g) → 6CO₂ (g) + 6H₂O (l) + Enegy
Hence, Respiration is aalso an Exothermic process as energy is produced during the reaction. 
Q. Write the chemical equation of burning of Magnesium wire in air. Is it an exothermic process?
Ans. When Magnesium wire burns in wire, Magnesium Oxide is produced along with heat and light energy. Hence, it is an exothermic reaction. 
2Mg (s) + O₂(g) → 2MgO (s) + Heat Energy + Light Energy
Q. Fill in the blanks
Decomposition of vegetables into  compost is an example of ___________ reaction.
Ans. Exothermic

ENDOTHERMIC REACTION
Those reactions in which heat is absorbed are known as Endothermic reactions. 
Q. What happens when Nitrogen and Oxygen are heated to a very high temperature? What type of reaction it is?
Ans. When Nitrogen and Oxygen are heated to a very high temperature it forms Nitrogen monoxide which is an endothermic reaction. 
N₂ (g) + O₂ (g) → 2NO (g)

"All the decomposition reactions are endothermic as they need energy to start the reaction"

(i). Like the decomposition of Calcium Carbonate is an endothermic reaction. 
(ii). Photosynthesis is also an endothermic reaction. 
(iii). Electrolysis of water to form hydrogen and oxygen is also a decomposition reaction. 

3. To indicate the conditions under which the reaction takes place. 
{If heat is required for a reaction to take place, then the heat sign delta (Δ) is put over the arrow of the equation. If the reaction takes place in the presence of a catalyst than the symbol or formula of the catalyst is also written above or below the arrow sign in the equation.}

1. When potassium chlorate (KClO₃) is heated in the presence of manganese dioxide (MnO₂) catalyst, it decomposes to form potassium chloride (KCl) and oxygen (O₂) gas.
2. Methanol (CH₃OH) is manufactured from carbon monoxide (CO) and hydrogen (H₂) under extreme pressure (300 atm) and temperature (300°C) and in the presence of ZnO + CrO₃
3. In photosynthesis, glucose is formed from Carbon Dioxide and Water under Sunlight and Chlorophyll as catalyst. 

Q. Convey the following information in the form of a balanced chemical equation:
On adding an aqueous solution of sodium hydroxide to an aqueous solution of copper sulphate copper hydroxide is precipitated and sodium sulphate remains in solution. 
Ans: NaOH (aq) + CuSO₄ (aq) ⟹ Cu(OH)₂ (s)↓ + Na₂SO₄ (aq)
It is an unbalanced equation. When balanced it becomes
2NaOH (aq) + CuSO₄ (aq) ⟹ Cu(OH)₂ (s)↓ + Na₂SO₄ (aq)

IRON OXIDES
There are two types of iron oxides. 
Iron (II) oxide FeO, and Iron (III) oxide Fe₂O₃
Iron (II) oxide FeO is known as Ferrous oxide.
Iron (III) oxide Fe₂O₃ is known as Ferric Oxide. 
Mixture of both the oxide is called Magnetic Iron Oxide (Fe₃O₄). 

Q. Write a balanced equation for the chemical reaction when heated iron metal reacts with steam to form iron (II, III) oxide and hydrogen. 

Ans. Fe (s) + H₂O (g) → Fe₃O₄ (s) + H₂ (g)
But it is an unbalanced equation, when balanced it becomes, 
3Fe (s) + 4H₂O (g) → Fe₃O₄ (s) + 4H₂ (g)

Q1. Translate the following statement into chemical equation and then balance the equation:
Hydrogen gas combines with nitrogen to form ammonia. 

Q2. Write the balanced chemical equation for the following reaction:
Sodium metal reacts with water to form sodium hydroxide and hydrogen. 

Q3. Write the balanced chemical equation for the following reaction:
(i) Aluminium reacts with copper chloride to form aluminium chloride and copper.
(ii) Aluminium hydroxide reacts with sulphuric acid to form Aluminium sulphate and water.
(iii) Manganese oxide reacts with hydrochloric acid to form manganese chloride, chlorine gas and water.

Q4. When the solution of substance X is added to a solution of potassium iodide, then a yellow solid separates out from the solution. 
a. What do you think substance X is likely to be?
b. Name the substance which the yellow solid consists of. 
c. Which characteristic of chemical reactions is illustrated by this example?
d. Write a balanced chemical equation for the reaction which takes place. Mention the physical states of all the reactants and products involved in the chemical equation. 

Tuesday 26 April 2022

Reference Solution Physics (LIGHT)

LECTURE 1: CHARACTERISTICS OF CHEMICAL REACTION (CLASS X)

CHEMICAL REACTIONS

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Chemical reactions are the processes in which new substances with new properties are formed. During a chemical reaction, atoms of one element do not change into those of another element. Only a rearrangement of atoms takes place in a chemical reaction. 
Example:
(i) When hydrogen combines with oxygen water is produced, which is different from hydrogen as well as oxygen, it is an example of chemical reaction.
(ii) The burning of magnesium in air to form magnesium oxide is an example of chemical reaction.
(iii) Souring of milk, Formation of curd from milk, Cooking of food, Digestion of food in our body, Process of respiration, Fermentation of grapes, Rusting of iron, Burning of fuels, Burning of candle wax, and Ripening of fruits are examples of chemical reactions. 

REACTANTS
The substances which take part in a chemical reaction are called reactants. 
PRODUCTS
The new substances produced as a result of chemical reaction are called products. 

CHARACTERISTICS OF CHEMICAL REACTION

The important characteristics of chemical reactions 

1. Evolution of a gas
When one of the products is a gas. 
Examples:
a. When zinc granules (Zn) reacts with dilute sulphuric acid (H₂SO₄) then zinc sulphate (ZnSO₄) and hydrogen gas (H₂) is produced. Here, hydrogen gas is evolved. 

b. When sodium carbonate Na₂CO₃ reacts with dilute hydrochloric acid HCl it produces carbon dioxide CO₂ gas. It is also an example of evolution of gas. 

2. Formation of a precipitate
When one of the products is insoluble in water.

a. When carbon-di-oxide CO₂ is passed through lime water CaO, Calcium Carbonate CaCO₃ is precipitated. 

b. When Potassium Iodide (KI) reacts with lead nitrate PbNO₃ then Potassium nitrate KNO₃ is formed which is insoluble in water hence precipitated. 

c. When Barium Chloride BaCl₂ reacts with sulphuric acid (H₂SO₄), white Barium Sulphate BaSO₄ is produced, which is insoluble in water and hence precipitated. 

3. Change in colour
When the products have different colours than that of the reactants. 

a. When citric acid mixed with purple coloured Potassium Permanganate, the solutions turned to be colourless. 

b. When sulphur di oxide gas reacts with acidified orange coloured potassium dichromate, the solution turned to be green. 

4. Change in temperature
Some chemical reactions are characterized by a change in temperature. For example, when quicklime (CaO) reacts with water, then slaked lime  Ca(OH)₂ is formed and a lot of heat energy is produced. Therefore, it is a chemical reaction which produces change in temperature. 
Exothermic Chemical Reaction 
The chemical reaction which produces heat when reaction occurs is called an exothermic chemical reaction. The temperature always increases during an exothermic chemical reactions.
Example: (i). CaO + H₂O → Ca(OH)₂ 
Quicklime reacts with water to produce slaked lime and heat
                 (ii). Zn + H₂SO₄ → ZnSO₄ + H₂
Zinc granules reacts with dilute sulphuric acid to produce zinc sulphate and hydrogen and heat. 
Endothermic Chemical Reaction
The chemical reactions which absorb heat during the reaction are called endothermic chemical reactions. 
Example: 
(i). N₂ + 3H₂ → 2NH₃
Nitrogen reacts with hydrogen to produce ammonia by absorbing heat from surrounding.
(ii). Ba(OH)₂ + NH₄Cl → BaCl₂ + NH₃ + H₂O
Barium hydroxide reacts with ammonium chloride to produce Barium chloride ammonia and water by absorbing heat from surrounding.

5. Change in state
Some chemical reactions are characterized by a change in state.
Example: When wax is burned, then water and carbon dioxide are formed. Thus, the combustion of wax is characterized by a change in state from solid to liquid and gas.